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Catalytic Oxidation of Benzoins by Hydrogen Peroxide on Nanosized HKUST-1: Influence of Substituents on the Reaction Rates and DFT Modeling of the Reaction Path

In this research, the oxidation of a series of benzoins, R-C(=O)-CH(OH)-R, where R = phenyl, 4-methoxyphenyl, 4-bromophenyl, and 2-naphthyl, by hydrogen peroxide in the presence of nanostructured HKUST-1 (suspension in acetonitrile/water mixture) was studied. The respective benzoic acids were the on...

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Detalles Bibliográficos
Autores principales: Yurchenko, Darya V., Lytvynenko, Anton S., Abdullayev, Emir N., Peregon, Nina V., Gavrilenko, Konstantin S., Gorlova, Alina O., Ryabukhin, Sergey V., Volochnyuk, Dmitriy M., Kolotilov, Sergey V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9861975/
https://www.ncbi.nlm.nih.gov/pubmed/36677805
http://dx.doi.org/10.3390/molecules28020747