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A Bridge too Far? Comparison of Transition Metal Complexes of Dibenzyltetraazamacrocycles with and without Ethylene Cross-Bridges: X-ray Crystal Structures, Kinetic Stability, and Electronic Properties

Tetraazamacrocycles, cyclic molecules with four nitrogen atoms, have long been known to produce highly stable transition metal complexes. Cross-bridging such molecules with two-carbon chains has been shown to enhance the stability of these complexes even further. This provides enough stability to us...

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Detalles Bibliográficos
Autores principales: Walker, Ashlie N., Ayala, Megan A., Mondal, Somrita, Bergagnini, Mackenzie C., Bui, Phuong John D., Chidester, Stephanie N., Doeden, Chad I., Esjornson, Louise, Sweany, Brian R., Garcia, Leslie, Krause, Jeanette A., Oliver, Allen G., Prior, Timothy J., Hubin, Timothy J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9863842/
https://www.ncbi.nlm.nih.gov/pubmed/36677952
http://dx.doi.org/10.3390/molecules28020895