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Electromechanically Coupled III-N Quantum Dots

We exploit the three-dimensional (3D) character of the strain field created around InGaN islands formed within the multilayer structures spaced by a less than 1-nm-thick GaN layer for the creation of spatially correlated electronically coupled quantum dots (QDs). The laterally inhomogeneous vertical...

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Autores principales: Barettin, Daniele, Sakharov, Alexei V., Tsatsulnikov, Andrey F., Nikolaev, Andrey E., Cherkashin, Nikolay
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9865564/
https://www.ncbi.nlm.nih.gov/pubmed/36677994
http://dx.doi.org/10.3390/nano13020241
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author Barettin, Daniele
Sakharov, Alexei V.
Tsatsulnikov, Andrey F.
Nikolaev, Andrey E.
Cherkashin, Nikolay
author_facet Barettin, Daniele
Sakharov, Alexei V.
Tsatsulnikov, Andrey F.
Nikolaev, Andrey E.
Cherkashin, Nikolay
author_sort Barettin, Daniele
collection PubMed
description We exploit the three-dimensional (3D) character of the strain field created around InGaN islands formed within the multilayer structures spaced by a less than 1-nm-thick GaN layer for the creation of spatially correlated electronically coupled quantum dots (QDs). The laterally inhomogeneous vertical out-diffusion of In atoms during growth interruption is the basic mechanism for the formation of InGaN islands within as-deposited 2D layers. An anisotropic 3D strain field created in the first layer is sufficient to justify the vertical correlation of the islands formed in the upper layers spaced by a sufficiently thin GaN layer. When the thickness of a GaN spacer exceeds 1 nm, QDs from different layers under the same growth conditions emit independently and in the same wavelength range. When extremely thin (less than 1 nm), a GaN spacer is formed solely by applying short GI, and a double wavelength emission in the blue and green spectral ranges evidences the electromechanical coupling. With [Formula: see text] calculations including electromechanical fields, we model the optoelectronic properties of a structure with three InGaN lens-shaped QDs embedded in a GaN matrix, with three different configurations of In content. The profiles of the band structures are strongly dependent on the In content arrangement, and the quantum-confined Stark effect is significantly reduced in a structure with an increasing gradient of In content from the top to the bottom QD. This configuration exhibits carrier tunneling through the QDs, an increase of wave functions overlap, and evidence emerges of three distinct peaks in the spectral range.
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spelling pubmed-98655642023-01-22 Electromechanically Coupled III-N Quantum Dots Barettin, Daniele Sakharov, Alexei V. Tsatsulnikov, Andrey F. Nikolaev, Andrey E. Cherkashin, Nikolay Nanomaterials (Basel) Article We exploit the three-dimensional (3D) character of the strain field created around InGaN islands formed within the multilayer structures spaced by a less than 1-nm-thick GaN layer for the creation of spatially correlated electronically coupled quantum dots (QDs). The laterally inhomogeneous vertical out-diffusion of In atoms during growth interruption is the basic mechanism for the formation of InGaN islands within as-deposited 2D layers. An anisotropic 3D strain field created in the first layer is sufficient to justify the vertical correlation of the islands formed in the upper layers spaced by a sufficiently thin GaN layer. When the thickness of a GaN spacer exceeds 1 nm, QDs from different layers under the same growth conditions emit independently and in the same wavelength range. When extremely thin (less than 1 nm), a GaN spacer is formed solely by applying short GI, and a double wavelength emission in the blue and green spectral ranges evidences the electromechanical coupling. With [Formula: see text] calculations including electromechanical fields, we model the optoelectronic properties of a structure with three InGaN lens-shaped QDs embedded in a GaN matrix, with three different configurations of In content. The profiles of the band structures are strongly dependent on the In content arrangement, and the quantum-confined Stark effect is significantly reduced in a structure with an increasing gradient of In content from the top to the bottom QD. This configuration exhibits carrier tunneling through the QDs, an increase of wave functions overlap, and evidence emerges of three distinct peaks in the spectral range. MDPI 2023-01-05 /pmc/articles/PMC9865564/ /pubmed/36677994 http://dx.doi.org/10.3390/nano13020241 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Barettin, Daniele
Sakharov, Alexei V.
Tsatsulnikov, Andrey F.
Nikolaev, Andrey E.
Cherkashin, Nikolay
Electromechanically Coupled III-N Quantum Dots
title Electromechanically Coupled III-N Quantum Dots
title_full Electromechanically Coupled III-N Quantum Dots
title_fullStr Electromechanically Coupled III-N Quantum Dots
title_full_unstemmed Electromechanically Coupled III-N Quantum Dots
title_short Electromechanically Coupled III-N Quantum Dots
title_sort electromechanically coupled iii-n quantum dots
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9865564/
https://www.ncbi.nlm.nih.gov/pubmed/36677994
http://dx.doi.org/10.3390/nano13020241
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AT cherkashinnikolay electromechanicallycouplediiinquantumdots