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How the Position of Substitution Affects Intermolecular Bonding in Halogen Derivatives of Carboranes: Crystal Structures of 1,2,3- and 8,9,12-Triiodo- and 8,9,12-Tribromo ortho-Carboranes

The crystal structures of two isomeric triiodo derivatives of ortho-carborane containing substituents in the three most electron-withdrawing positions of the carborane cage, 1,2,3-I(3)-1,2-C(2)B(10)H(9), and the three most electron-donating positions, 8,9,12-I(3)-1,2-C(2)B(10)H(9), as well as the cr...

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Detalles Bibliográficos
Autores principales: Suponitsky, Kyrill Yu., Anufriev, Sergey A., Sivaev, Igor B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9865681/
https://www.ncbi.nlm.nih.gov/pubmed/36677932
http://dx.doi.org/10.3390/molecules28020875