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Quantitative evaluation of the actual hydrogen atom donating activities of O–H bonds in phenols: structure–activity relationship
The H-donating activity of phenol and the H-abstraction activity of phenol radicals have been extensively studied. In this article, the second-order rate constants of 25 hydrogen atom transfer (HAT) reactions between phenols and PINO and DPPH radicals in acetonitrile at 298 K were studied. Thermo-ki...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9869660/ https://www.ncbi.nlm.nih.gov/pubmed/36756400 http://dx.doi.org/10.1039/d2ra06877j |