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Quantitative evaluation of the actual hydrogen atom donating activities of O–H bonds in phenols: structure–activity relationship

The H-donating activity of phenol and the H-abstraction activity of phenol radicals have been extensively studied. In this article, the second-order rate constants of 25 hydrogen atom transfer (HAT) reactions between phenols and PINO and DPPH radicals in acetonitrile at 298 K were studied. Thermo-ki...

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Detalles Bibliográficos
Autores principales: Fu, Yan-Hua, Zhang, Yanwei, Wang, Fang, Zhao, Ling, Shen, Guang-Bin, Zhu, Xiao-Qing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9869660/
https://www.ncbi.nlm.nih.gov/pubmed/36756400
http://dx.doi.org/10.1039/d2ra06877j