Synthesis and Stereodynamic and Emission Properties of Dissymmetric Bis-Aryl Carbazole Boranes and Identification of a CPL-Active B–C Atropisomeric Compound

[Image: see text] We synthesized bis-aryl carbazole borane derivatives having emissive properties and axial chirality. The resolution of a thermally stable atropisomeric pair (compound 1b), due to a B–C chiral axis, was achieved by chiral stationary-phase high-performance liquid chromatography (CSP-...

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Detalles Bibliográficos
Autores principales: Pecorari, Daniel, Giuliani, Emanuele, Mazzanti, Andrea, Stagni, Stefano, Fiorini, Valentina, Vigarani, Giulia, Zinna, Francesco, Pescitelli, Gennaro, Mancinelli, Michele
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9872089/
https://www.ncbi.nlm.nih.gov/pubmed/36599041
http://dx.doi.org/10.1021/acs.joc.2c02209

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9872089/
https://www.ncbi.nlm.nih.gov/pubmed/36599041
http://dx.doi.org/10.1021/acs.joc.2c02209

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