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Synthesis and Stereodynamic and Emission Properties of Dissymmetric Bis-Aryl Carbazole Boranes and Identification of a CPL-Active B–C Atropisomeric Compound
[Image: see text] We synthesized bis-aryl carbazole borane derivatives having emissive properties and axial chirality. The resolution of a thermally stable atropisomeric pair (compound 1b), due to a B–C chiral axis, was achieved by chiral stationary-phase high-performance liquid chromatography (CSP-...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9872089/ https://www.ncbi.nlm.nih.gov/pubmed/36599041 http://dx.doi.org/10.1021/acs.joc.2c02209 |