Comparison of Two Zinc Hydride Precatalysts for Selective Dehydrogenative Borylation of Terminal Alkynes: A Detailed Mechanistic Study

[Image: see text] The conjugated bis-guanidinate-stabilized zinc hydride complex (I)-precatalyzed chemoselective dehydroborylation of a wide array of terminal alkynes with excellent yields is reported. Further, precatalyst I is compared with a newly synthesized (Diethyl)NacNac zinc hydride precataly...

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Detalles Bibliográficos
Autores principales: Sahoo, Rajata Kumar, Patro, Arukela Ganesh, Sarkar, Nabin, Nembenna, Sharanappa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9878541/
https://www.ncbi.nlm.nih.gov/pubmed/36713704
http://dx.doi.org/10.1021/acsomega.2c07381

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9878541/
https://www.ncbi.nlm.nih.gov/pubmed/36713704
http://dx.doi.org/10.1021/acsomega.2c07381

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