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Comparison of Two Zinc Hydride Precatalysts for Selective Dehydrogenative Borylation of Terminal Alkynes: A Detailed Mechanistic Study
[Image: see text] The conjugated bis-guanidinate-stabilized zinc hydride complex (I)-precatalyzed chemoselective dehydroborylation of a wide array of terminal alkynes with excellent yields is reported. Further, precatalyst I is compared with a newly synthesized (Diethyl)NacNac zinc hydride precataly...
Autores principales: | Sahoo, Rajata Kumar, Patro, Arukela Ganesh, Sarkar, Nabin, Nembenna, Sharanappa |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9878541/ https://www.ncbi.nlm.nih.gov/pubmed/36713704 http://dx.doi.org/10.1021/acsomega.2c07381 |
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