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Analysis of Temperature-Programmed Desorption via Equilibrium Thermodynamics

[Image: see text] Temperature-programmed desorption (TPD) experiments in surface science are usually analyzed using the Polanyi–Wigner equation and/or transition-state theory. These methods are far from straightforward, and the determination of the pre-exponential factor is often problematic. We pre...

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Detalles Bibliográficos
Autores principales: Schmid, Michael, Parkinson, Gareth S., Diebold, Ulrike
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9881163/
https://www.ncbi.nlm.nih.gov/pubmed/36718262
http://dx.doi.org/10.1021/acsphyschemau.2c00031