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Synthesis of the ABC Ring of Calyciphylline A-Type Alkaloids by a Stereocontrolled Aldol Cyclization: Formal Synthesis of (±)-Himalensine A

[Image: see text] A synthetic approach to a functionalized ABC-tricyclic framework of calyciphilline A-type alkaloids, a building block toward this class of alkaloids, is reported. The key synthetic steps involve a radical cyclization to form the hydroindole system and piperidine ring closure throug...

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Detalles Bibliográficos
Autores principales: Marquès, Clàudia, Diaba, Faïza, Gómez-Bengoa, Enrique, Bonjoch, Josep
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9881646/
https://www.ncbi.nlm.nih.gov/pubmed/35862855
http://dx.doi.org/10.1021/acs.joc.2c01171