B(C(6)F(5))(3)-Catalyzed Diastereoselective and Divergent Reactions of Vinyldiazo Esters with Nitrones: Synthesis of Highly Functionalized Diazo Compounds

[Image: see text] Herein we report a mild, transition-metal-free, highly diastereoselective Lewis acid catalyzed methodology toward the synthesis of isoxazolidine-based diazo compounds from the reaction between vinyldiazo esters and nitrones. Interestingly, the isoxazolidine products were identified...

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Detalles Bibliográficos
Autores principales: Stefkova, Katarina, Guerzoni, Michael G., van Ingen, Yara, Richards, Emma, Melen, Rebecca L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9887602/
https://www.ncbi.nlm.nih.gov/pubmed/36634071
http://dx.doi.org/10.1021/acs.orglett.2c04198

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9887602/
https://www.ncbi.nlm.nih.gov/pubmed/36634071
http://dx.doi.org/10.1021/acs.orglett.2c04198

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