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Reductive Elimination Reactions in Gold(III) Complexes Leading to C(sp(3))–X (X = C, N, P, O, Halogen) Bond Formation: Inner-Sphere vs S(N)2 Pathways

[Image: see text] The reactions leading to the formation of C–heteroatom bonds in the coordination sphere of Au(III) complexes are uncommon, and their mechanisms are not well known. This work reports on the synthesis and reductive elimination reactions of a series of Au(III) methyl complexes contain...

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Detalles Bibliográficos
Autores principales: Portugués, Alejandro, Martínez-Nortes, Miguel Ángel, Bautista, Delia, González-Herrero, Pablo, Gil-Rubio, Juan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9890567/
https://www.ncbi.nlm.nih.gov/pubmed/36658748
http://dx.doi.org/10.1021/acs.inorgchem.2c04166