Cargando…
Reductive Elimination Reactions in Gold(III) Complexes Leading to C(sp(3))–X (X = C, N, P, O, Halogen) Bond Formation: Inner-Sphere vs S(N)2 Pathways
[Image: see text] The reactions leading to the formation of C–heteroatom bonds in the coordination sphere of Au(III) complexes are uncommon, and their mechanisms are not well known. This work reports on the synthesis and reductive elimination reactions of a series of Au(III) methyl complexes contain...
Autores principales: | Portugués, Alejandro, Martínez-Nortes, Miguel Ángel, Bautista, Delia, González-Herrero, Pablo, Gil-Rubio, Juan |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9890567/ https://www.ncbi.nlm.nih.gov/pubmed/36658748 http://dx.doi.org/10.1021/acs.inorgchem.2c04166 |
Ejemplares similares
-
Short X···N Halogen Bonds With Hexamethylenetetraamine as the Acceptor
por: Anyfanti, Goulielmina, et al.
Publicado: (2021) -
Halogen Bonding in Sulphonamide Co-Crystals: X···π Preferred over X···O/N?
por: Heinen, Tobias, et al.
Publicado: (2023) -
C(sp
(n))−X (n=1–3) Bond Activation by Palladium
por: Hansen, Thomas, et al.
Publicado: (2022) -
Enhancing Effects of the Cyano Group on the C-X∙∙∙N Hydrogen or Halogen Bond in Complexes of X-Cyanomethanes with Trimethyl Amine: CH(3−n)(CN)(n)X∙∙∙NMe(3), (n = 0–3; X = H, Cl, Br, I)
por: Parra, Rubén D., et al.
Publicado: (2022) -
Multicenter (FX)(n)/NH(3) Halogen Bonds (X = Cl, Br and n = 1–5). QTAIM Descriptors of the Strength of the X∙∙∙N Interaction
por: Buralli, Gabriel J., et al.
Publicado: (2017)