Inherently chiral calixarenes by a catalytic enantioselective desymmetrizing cross-dehydrogenative coupling

Under the catalysis of PdBr(2) and a chiral phosphoramidite ligand, the upper-rim mono (2-bromoaroyl)-substituted calix[4]arene derivatives underwent a facile enantioselective desymmetrization reaction to afford 9H-fluorene-embedded inherently chiral calixarenes in good yields with excellent enantio...

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Detalles Bibliográficos
Autores principales: Zhang, Xin, Tong, Shuo, Zhu, Jieping, Wang, Mei-Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9890570/
https://www.ncbi.nlm.nih.gov/pubmed/36755707
http://dx.doi.org/10.1039/d2sc06234h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9890570/
https://www.ncbi.nlm.nih.gov/pubmed/36755707
http://dx.doi.org/10.1039/d2sc06234h

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