A versatile strategy for the formation of hydride-bridged actinide–iridium multimetallics

Reaction of the potassium pentamethylcyclopentadienyl iridate tris-hydride K[IrCp*H(3)] with UCl(4) and ThCl(4)(DME)(2) led to the complete replacement of the halide ligands to generate multimetallic complexes U{(μ-H)(3)IrCp*}(4) (1) and Th{[(μ-H(2))(H)IrCp*](2)[(μ-H)(3)IrCp*](2)} (2), respectively....

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Detalles Bibliográficos
Autores principales: Ye, Christopher Z., Del Rosal, Iker, Boreen, Michael A., Ouellette, Erik T., Russo, Dominic R., Maron, Laurent, Arnold, John, Camp, Clément
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9890599/
https://www.ncbi.nlm.nih.gov/pubmed/36755711
http://dx.doi.org/10.1039/d2sc04903a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9890599/
https://www.ncbi.nlm.nih.gov/pubmed/36755711
http://dx.doi.org/10.1039/d2sc04903a

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