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A versatile strategy for the formation of hydride-bridged actinide–iridium multimetallics
Reaction of the potassium pentamethylcyclopentadienyl iridate tris-hydride K[IrCp*H(3)] with UCl(4) and ThCl(4)(DME)(2) led to the complete replacement of the halide ligands to generate multimetallic complexes U{(μ-H)(3)IrCp*}(4) (1) and Th{[(μ-H(2))(H)IrCp*](2)[(μ-H)(3)IrCp*](2)} (2), respectively....
Autores principales: | Ye, Christopher Z., Del Rosal, Iker, Boreen, Michael A., Ouellette, Erik T., Russo, Dominic R., Maron, Laurent, Arnold, John, Camp, Clément |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9890599/ https://www.ncbi.nlm.nih.gov/pubmed/36755711 http://dx.doi.org/10.1039/d2sc04903a |
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