Visible-light-induced organocatalytic enantioselective N–H insertion of α-diazoesters enabled by indirect free carbene capture

While asymmetric insertion of metal carbenes into H–X (X = C, N, O, etc.) bonds has been well-established, asymmetric control over free carbenes is challenging due to the presence of strong background reactions and lack of any anchor for a catalyst interaction. Here we have achieved the first photo-...

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Detalles Bibliográficos
Autores principales: Guo, Wengang, Zhou, Ying, Xie, Hongling, Yue, Xin, Jiang, Feng, Huang, Hai, Han, Zhengyu, Sun, Jianwei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9890670/
https://www.ncbi.nlm.nih.gov/pubmed/36755716
http://dx.doi.org/10.1039/d2sc05149d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9890670/
https://www.ncbi.nlm.nih.gov/pubmed/36755716
http://dx.doi.org/10.1039/d2sc05149d

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