Multifaceted behavior of a doubly reduced arylborane in B–H-bond activation and hydroboration catalysis

Alkali-metal salts of 9,10-dimethyl-9,10-dihydro-9,10-diboraanthrancene (M(2)[DBA-Me(2)]; M(+) = Li(+), Na(+), K(+)) activate the H–B bond of pinacolborane (HBpin) in THF already at room temperature. For M(+) = Na(+), K(+), the addition products M(2)[4] are formed, which contain one new H–B and one...

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Detalles Bibliográficos
Autores principales: Prey, Sven E., Herok, Christoph, Fantuzzi, Felipe, Bolte, Michael, Lerner, Hans-Wolfram, Engels, Bernd, Wagner, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9890859/
https://www.ncbi.nlm.nih.gov/pubmed/36755708
http://dx.doi.org/10.1039/d2sc05518j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9890859/
https://www.ncbi.nlm.nih.gov/pubmed/36755708
http://dx.doi.org/10.1039/d2sc05518j

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