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Multifaceted behavior of a doubly reduced arylborane in B–H-bond activation and hydroboration catalysis
Alkali-metal salts of 9,10-dimethyl-9,10-dihydro-9,10-diboraanthrancene (M(2)[DBA-Me(2)]; M(+) = Li(+), Na(+), K(+)) activate the H–B bond of pinacolborane (HBpin) in THF already at room temperature. For M(+) = Na(+), K(+), the addition products M(2)[4] are formed, which contain one new H–B and one...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9890859/ https://www.ncbi.nlm.nih.gov/pubmed/36755708 http://dx.doi.org/10.1039/d2sc05518j |