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Radical-like reactivity for dihydrogen activation by coinage metal–aluminyl complexes: computational evidence inspired by experimental main group chemistry
The computational study of an unprecedented reactivity of coinage metal–aluminyl complexes with dihydrogen is reported. In close resemblance to group 14 dimetallenes and dimetallynes, the complexes are predicted to activate H(2) under mild conditions. Two different reaction pathways are found disclo...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9890964/ https://www.ncbi.nlm.nih.gov/pubmed/36755722 http://dx.doi.org/10.1039/d2sc05815d |