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Radical-like reactivity for dihydrogen activation by coinage metal–aluminyl complexes: computational evidence inspired by experimental main group chemistry

The computational study of an unprecedented reactivity of coinage metal–aluminyl complexes with dihydrogen is reported. In close resemblance to group 14 dimetallenes and dimetallynes, the complexes are predicted to activate H(2) under mild conditions. Two different reaction pathways are found disclo...

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Detalles Bibliográficos
Autores principales: Sorbelli, Diego, Belpassi, Leonardo, Belanzoni, Paola
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9890964/
https://www.ncbi.nlm.nih.gov/pubmed/36755722
http://dx.doi.org/10.1039/d2sc05815d

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