Experimental and computational insights into the mechanism of FLP mediated selective C–F bond activation

Frustrated Lewis pairs (FLP) comprising of B(C(6)F(5))(3) (BCF) and 2,4,6-triphenylpyridine (TPPy), P(o-Tol)(3) or tetrahydrothiophene (THT) have been shown to mediate selective C–F activation in both geminal and chemically equivalent distal C–F sites. In comparison to other reported attempts of C–F...

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Detalles Bibliográficos
Autores principales: Gupta, Richa, Csókás, Dániel, Lye, Kenneth, Young, Rowan D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9891352/
https://www.ncbi.nlm.nih.gov/pubmed/36756325
http://dx.doi.org/10.1039/d2sc05632a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9891352/
https://www.ncbi.nlm.nih.gov/pubmed/36756325
http://dx.doi.org/10.1039/d2sc05632a

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