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C(sp(3))–H cyanation by a formal copper(iii) cyanide complex
High-valent metal oxo complexes are prototypical intermediates for the activation and hydroxylation of alkyl C–H bonds. Substituting the oxo ligand with other functional groups offers the opportunity for additional C–H functionalization beyond C–O bond formation. However, few species aside from meta...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9891353/ https://www.ncbi.nlm.nih.gov/pubmed/36756315 http://dx.doi.org/10.1039/d2sc06573h |