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C(sp(3))–H cyanation by a formal copper(iii) cyanide complex

High-valent metal oxo complexes are prototypical intermediates for the activation and hydroxylation of alkyl C–H bonds. Substituting the oxo ligand with other functional groups offers the opportunity for additional C–H functionalization beyond C–O bond formation. However, few species aside from meta...

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Detalles Bibliográficos
Autores principales: Bower, Jamey K., Reese, Maxwell S., Mazin, Ilia M., Zarnitsa, Lina M., Cypcar, Andrew D., Moore, Curtis E., Sokolov, Alexander Yu., Zhang, Shiyu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9891353/
https://www.ncbi.nlm.nih.gov/pubmed/36756315
http://dx.doi.org/10.1039/d2sc06573h