Bond breaking of furan–maleimide adducts via a diradical sequential mechanism under an external mechanical force

Substituted furan–maleimide Diels–Alder adducts are bound by dynamic covalent bonds that make them particularly attractive mechanophores. Thermally activated [4 + 2] retro-Diels–Alder (DA) reactions predominantly proceed via a concerted mechanism in the ground electronic state. We show that an asymm...

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Detalles Bibliográficos
Autores principales: Cardosa-Gutierrez, Manuel, De Bo, Guillaume, Duwez, Anne-Sophie, Remacle, Francoise
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9891376/
https://www.ncbi.nlm.nih.gov/pubmed/36756317
http://dx.doi.org/10.1039/d2sc05051j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9891376/
https://www.ncbi.nlm.nih.gov/pubmed/36756317
http://dx.doi.org/10.1039/d2sc05051j

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