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A Ni-catalyzed asymmetric C(sp)–P cross-coupling reaction for the synthesis of P-stereogenic alkynylphosphines

Due to the high reactivity of the triple bond, P-stereogenic alkynylphosphines could be easily derivatized, serving as universal building blocks for structurally diverse phosphine compounds. However, the synthesis of alkynylphosphines via direct P–C bond formation was unprecedented. Here, we report...

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Detalles Bibliográficos
Autores principales: Zhang, Bin, Zhou, Wen-Qing, Liu, Xu-Teng, Sun, Yingying, Zhang, Qing-Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9891383/
https://www.ncbi.nlm.nih.gov/pubmed/36756330
http://dx.doi.org/10.1039/d2sc05841c