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Mechanistic Insights into Molecular Crystalline Organometallic Heterogeneous Catalysis through Parahydrogen-Based Nuclear Magnetic Resonance Studies
[Image: see text] The heterogeneous solid–gas reactions of crystals of [Rh(L(2))(propene)][BAr(F)(4)] (1, L(2) = (t)Bu(2)PCH(2)CH(2)P(t)Bu(2)) with H(2) and propene, 1-butene, propyne, or 1-butyne are explored by gas-phase nuclear magnetic resonance (NMR) spectroscopy under batch conditions at 25 °C...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9896567/ https://www.ncbi.nlm.nih.gov/pubmed/36688560 http://dx.doi.org/10.1021/jacs.2c12642 |