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Mechanistic Insights into Molecular Crystalline Organometallic Heterogeneous Catalysis through Parahydrogen-Based Nuclear Magnetic Resonance Studies

[Image: see text] The heterogeneous solid–gas reactions of crystals of [Rh(L(2))(propene)][BAr(F)(4)] (1, L(2) = (t)Bu(2)PCH(2)CH(2)P(t)Bu(2)) with H(2) and propene, 1-butene, propyne, or 1-butyne are explored by gas-phase nuclear magnetic resonance (NMR) spectroscopy under batch conditions at 25 °C...

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Detalles Bibliográficos
Autores principales:	Gyton, Matthew R., Royle, Cameron G., Beaumont, Simon K., Duckett, Simon B., Weller, Andrew S.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9896567/ https://www.ncbi.nlm.nih.gov/pubmed/36688560 http://dx.doi.org/10.1021/jacs.2c12642

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