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Emergence of a proton exchange-based isomerization and lactonization mechanism in the plant coumarin synthase COSY
Plants contain rapidly evolving specialized enzymes that support the biosynthesis of functionally diverse natural products. In coumarin biosynthesis, a BAHD acyltransferase-family enzyme COSY was recently discovered to accelerate coumarin formation as the only known BAHD enzyme to catalyze an intram...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9898226/ https://www.ncbi.nlm.nih.gov/pubmed/36737607 http://dx.doi.org/10.1038/s41467-023-36299-1 |