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Regioselectivity of concerted proton–electron transfer at the surface of a polyoxovanadate cluster
Proton-coupled electron transfer (PCET) is an important process in the activation and reactivity of metal oxide surfaces. In this work, we study the electronic structure of a reduced polyoxovanadate-alkoxide cluster bearing a single bridging oxide moiety. The structural and electronic implications o...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9906639/ https://www.ncbi.nlm.nih.gov/pubmed/36794190 http://dx.doi.org/10.1039/d2sc05928b |