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Regioselectivity of concerted proton–electron transfer at the surface of a polyoxovanadate cluster

Proton-coupled electron transfer (PCET) is an important process in the activation and reactivity of metal oxide surfaces. In this work, we study the electronic structure of a reduced polyoxovanadate-alkoxide cluster bearing a single bridging oxide moiety. The structural and electronic implications o...

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Detalles Bibliográficos
Autores principales: Schreiber, Eric, Brennessel, William W., Matson, Ellen M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9906639/
https://www.ncbi.nlm.nih.gov/pubmed/36794190
http://dx.doi.org/10.1039/d2sc05928b

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