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On-surface synthesis of non-benzenoid conjugated polymers by selective atomic rearrangement of ethynylarenes

Here, we report a new on-surface synthetic strategy to precisely introduce five-membered units into conjugated polymers from specifically designed precursor molecules that give rise to low-bandgap fulvalene-bridged bisanthene polymers. The selective formation of non-benzenoid units is finely control...

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Detalles Bibliográficos
Autores principales: Jiménez-Martín, Alejandro, Villalobos, Federico, Mallada, Benjamin, Edalatmanesh, Shayan, Matěj, Adam, Cuerva, Juan M., Jelínek, Pavel, Campaña, Araceli G., de la Torre, Bruno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9906656/
https://www.ncbi.nlm.nih.gov/pubmed/36794197
http://dx.doi.org/10.1039/d2sc04722e