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Maximized axial helicity in a Pd(2)L(4) cage: inverse guest size-dependent compression and mesocate isomerism

Helicity is an archetypal structural motif of many biological systems and provides a basis for molecular recognition in DNA. Whilst artificial supramolecular hosts are often helical, the relationship between helicity and guest encapsulation is not well understood. We report a detailed study on a sig...

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Detalles Bibliográficos
Autores principales: Bloch, Witold M., Horiuchi, Shinnosuke, Holstein, Julian J., Drechsler, Christoph, Wuttke, Axel, Hiller, Wolf, Mata, Ricardo A., Clever, Guido H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9906678/
https://www.ncbi.nlm.nih.gov/pubmed/36794203
http://dx.doi.org/10.1039/d2sc06629g