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Mapping the effect of configuration and protecting group pattern on glycosyl acceptor reactivity

The reactivity of the acceptor alcohol can have a tremendous influence on the outcome of a glycosylation reaction, both in terms of yield and stereoselectivity. Through a systematic survey of 67 acceptor alcohols in glycosylation reactions with two glucosyl donors we here reveal how the reactivity o...

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Detalles Bibliográficos
Autores principales: van Hengst, Jacob M. A., Hellemons, Rik J. C., Remmerswaal, Wouter A., van de Vrande, Koen N. A., Hansen, Thomas, van der Vorm, Stefan, Overkleeft, Hermen S., van der Marel, Gijsbert A., Codée, Jeroen D. C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9906709/
https://www.ncbi.nlm.nih.gov/pubmed/36794180
http://dx.doi.org/10.1039/d2sc06139b