Cargando…
Connecting Thermodynamics and Kinetics of Proton Coupled Electron Transfer at Polyoxovanadate Surfaces Using the Marcus Cross Relation
[Image: see text] Here, we evaluate the efficacy of multiple methods for elucidating the average bond dissociation free energy (BDFE) of two surface hydroxide moieties in a reduced polyoxovanadate cluster, [V(6)O(11)(OH)(2)(TRIOL(NO2))(2)](−2). Through cyclic voltammetry, individual thermochemical p...
| Autores principales: | , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9906739/ https://www.ncbi.nlm.nih.gov/pubmed/36049052 http://dx.doi.org/10.1021/acs.inorgchem.2c02541 |