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Phonon confinement and particle size effect on the low-frequency Raman mode of aurivillius phase Bi(4)Ti(3)O(12) powders

We report the systematic measurements in bismuth titanate powders of Raman frequency shift, ω and full width at half maximum (FWHM), Γ of optical phonons at q = 0 obtained between ∼300 K and 673 K in air. Both the particle size and phonon confinement effects are reasonably satisfactory to explain th...

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Detalles Bibliográficos
Autores principales: Amaechi, Ifeanyichukwu C., Ruediger, Andreas, Pignolet, Alain
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9906980/
https://www.ncbi.nlm.nih.gov/pubmed/36762079
http://dx.doi.org/10.1039/d2ra06297f