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Compound I Formation and Reactivity in Dimeric Chlorite Dismutase: Impact of pH and the Dynamics of the Catalytic Arginine

[Image: see text] The heme enzyme chlorite dismutase (Cld) catalyzes the degradation of chlorite to chloride and dioxygen. Many questions about the molecular reaction mechanism of this iron protein have remained unanswered, including the electronic nature of the catalytically relevant oxoiron(IV) in...

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Detalles Bibliográficos
Autores principales: Schmidt, Daniel, Falb, Nikolaus, Serra, Ilenia, Bellei, Marzia, Pfanzagl, Vera, Hofbauer, Stefan, Van Doorslaer, Sabine, Battistuzzi, Gianantonio, Furtmüller, Paul G., Obinger, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9910045/
https://www.ncbi.nlm.nih.gov/pubmed/36706455
http://dx.doi.org/10.1021/acs.biochem.2c00696