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The Perfluoro Cage Effect: A Search for Electron-Encapsulating Molecules
[Image: see text] Quantum chemical calculations have for some time predicted that perfluorinated polyhedral organic molecules should exhibit a low-energy LUMO consisting of the overlapping inward-pointing lobes of the C–F σ* orbitals. Accordingly, these molecules should be able to encapsulate an ele...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9910065/ https://www.ncbi.nlm.nih.gov/pubmed/36777561 http://dx.doi.org/10.1021/acsomega.2c07374 |