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Aromatic-bridged and meso-meso-linked BF(2)-smaragdyrin dimers exhibit fast decays in polar solvents by symmetry-breaking charge transfer

Symmetry-breaking charge transfer is one of the key process in photosynthetic reaction centers and specific artificial optoelectronic devices such as dye-sensitized solar cells. Here we report the synthesis of aromatic-bridged BF(2)-smaragdyrin dimers, meso-free BF(2)-smaragdyrin, and its meso-meso-...

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Detalles Bibliográficos
Autores principales: Wen, Lingbo, Cao, Xian, Lee, Seokwon, Xu, Ling, Rao, Yutao, Kang, Seongsoo, Kim, Dongho, Osuka, Atsuhiro, Song, Jianxin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9911704/
https://www.ncbi.nlm.nih.gov/pubmed/36759744
http://dx.doi.org/10.1038/s42004-023-00822-8