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Probing Methyl Group Tunneling in [(CH(3))(2)NH(2)][Zn(HCOO)(3)] Hybrid Perovskite Using Co(2+) EPR

At low temperature, methyl groups act as hindered quantum rotors exhibiting rotational quantum tunneling, which is highly sensitive to a local methyl group environment. Recently, we observed this effect using pulsed electron paramagnetic resonance (EPR) in two dimethylammonium-containing hybrid pero...

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Detalles Bibliográficos
Autores principales: Usevičius, Gediminas, Eggeling, Andrea, Pocius, Ignas, Kalendra, Vidmantas, Klose, Daniel, Mączka, Mirosław, Pöppl, Andreas, Banys, Jūras, Jeschke, Gunnar, Šimėnas, Mantas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9920925/
https://www.ncbi.nlm.nih.gov/pubmed/36770643
http://dx.doi.org/10.3390/molecules28030979