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Probing Methyl Group Tunneling in [(CH(3))(2)NH(2)][Zn(HCOO)(3)] Hybrid Perovskite Using Co(2+) EPR
At low temperature, methyl groups act as hindered quantum rotors exhibiting rotational quantum tunneling, which is highly sensitive to a local methyl group environment. Recently, we observed this effect using pulsed electron paramagnetic resonance (EPR) in two dimethylammonium-containing hybrid pero...
Autores principales: | Usevičius, Gediminas, Eggeling, Andrea, Pocius, Ignas, Kalendra, Vidmantas, Klose, Daniel, Mączka, Mirosław, Pöppl, Andreas, Banys, Jūras, Jeschke, Gunnar, Šimėnas, Mantas |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9920925/ https://www.ncbi.nlm.nih.gov/pubmed/36770643 http://dx.doi.org/10.3390/molecules28030979 |
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