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Anaerobic demethylation of guaiacyl-derived monolignols enabled by a designed artificial cobalamin methyltransferase fusion enzyme

Lignin-derived aryl methyl ethers (e.g. coniferyl alcohol, ferulic acid) are expected to be a future carbon source for chemistry. The well-known P450 dependent biocatalytic O-demethylation of these aryl methyl ethers is prone to side product formation especially for the oxidation sensitive catechol...

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Detalles Bibliográficos
Autores principales: Grimm, Christopher, Pompei, Simona, Egger, Kristina, Fuchs, Michael, Kroutil, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9930637/
https://www.ncbi.nlm.nih.gov/pubmed/36816070
http://dx.doi.org/10.1039/d2ra08005b