Activation of perfluoroalkyl iodides by anions: extending the scope of halogen bond activation to C(sp(3))–H amidation, C(sp(2))–H iodination, and perfluoroalkylation reactions

A simple, efficient, and convenient activation of perfluoroalkyl iodides by tBuONa or KOH, without expensive photo- or transition metal catalysts, allows the promotion of versatile α-sp(3) C–H amidation reactions of alkyl ethers and benzylic hydrocarbons, C–H iodination of heteroaryl compounds, and...

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Detalles Bibliográficos
Autores principales: Wang, Yaxin, Cao, Zehui, He, Qin, Huang, Xin, Liu, Jiaxi, Neumann, Helfried, Chen, Gong, Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9930934/
https://www.ncbi.nlm.nih.gov/pubmed/36819859
http://dx.doi.org/10.1039/d2sc06145g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9930934/
https://www.ncbi.nlm.nih.gov/pubmed/36819859
http://dx.doi.org/10.1039/d2sc06145g

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