Cargando…

Activation of perfluoroalkyl iodides by anions: extending the scope of halogen bond activation to C(sp(3))–H amidation, C(sp(2))–H iodination, and perfluoroalkylation reactions

A simple, efficient, and convenient activation of perfluoroalkyl iodides by tBuONa or KOH, without expensive photo- or transition metal catalysts, allows the promotion of versatile α-sp(3) C–H amidation reactions of alkyl ethers and benzylic hydrocarbons, C–H iodination of heteroaryl compounds, and...

Descripción completa

Detalles Bibliográficos
Autores principales:	Wang, Yaxin, Cao, Zehui, He, Qin, Huang, Xin, Liu, Jiaxi, Neumann, Helfried, Chen, Gong, Beller, Matthias
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9930934/ https://www.ncbi.nlm.nih.gov/pubmed/36819859 http://dx.doi.org/10.1039/d2sc06145g

Ejemplares similares

Perfluoroalkylation of Aryl-N,N-dimethyl Hydrazones Using Hypervalent Iodine(III) Reagents or Perfluoroalkyl Iodides
por: Janhsen, Benjamin, et al.
Publicado: (2017)

Photocatalytic redox-neutral selective single C(sp(3))–F bond activation of perfluoroalkyl iminosulfides with alkenes and water
por: Wang, Tao, et al.
Publicado: (2023)

Benchmarking of Halogen Bond Strength in Solution with Nickel Fluorides: Bromine versus Iodine and Perfluoroaryl versus Perfluoroalkyl Donors
por: Pike, Sarah J., et al.
Publicado: (2019)

A unified photoredox-catalysis strategy for C(sp(3))–H hydroxylation and amidation using hypervalent iodine
por: Li, Guo-Xing, et al.
Publicado: (2017)

Visible Light-Induced Homolytic Cleavage of Perfluoroalkyl Iodides Mediated by Phosphines
por: Bracker, Mario, et al.
Publicado: (2020)

A photoexcited halogen-bonded EDA complex of the thiophenolate anion with iodobenzene for C(sp(3))–H activation and thiolation
por: Li, Tao, et al.
Publicado: (2021)

Correction: A photoexcited halogen-bonded EDA complex of the thiophenolate anion with iodobenzene for C(sp(3))–H activation and thiolation
por: Li, Tao, et al.
Publicado: (2021)

Dehydration of (Perfluoroalkyl)tetramethylcyclopentenol
por: Čermák, Jan, et al.
Publicado: (2011)

Historical Trend of Exposure to Perfluoroalkyl Surfactants PFOA, ADV, and cC(6)O(4) and its Management in Two Perfluoroalkyl Polymers Plants, Italy
por: Fustinoni, Silvia, et al.
Publicado: (2023)

Kinetics of Excretion of the Perfluoroalkyl Surfactant cC(6)O(4) in Humans
por: Fustinoni, Silvia, et al.
Publicado: (2023)

Synthesis of Fluorinated Amide Derivatives via a Radical N-Perfluoroalkylation–Defluorination Pathway
por: Zheng, Zhiyao, et al.
Publicado: (2020)

Directed C(sp(3))–H arylation of tryptophan: transformation of the directing group into an activated amide
por: Nicke, Lennart, et al.
Publicado: (2019)

A general strategy for the synthesis of α-trifluoromethyl- and α-perfluoroalkyl-β-lactams via palladium-catalyzed carbonylation
por: Li, Yang, et al.
Publicado: (2021)

Perfluoroalkyl and polyfluoroalkyl substances in consumer products
por: Kotthoff, Matthias, et al.
Publicado: (2015)

Association of Perfluoroalkyl and Polyfluoroalkyl Substances With Adiposity
por: Cardenas, Andres, et al.
Publicado: (2018)

Structurally Well-Defined Anion-Exchange Membranes Containing Perfluoroalkyl and Ammonium-Functionalized Fluorenyl Groups
por: Ozawa, Mizuki, et al.
Publicado: (2018)

Perfluoroalkyl substances (PFASs) are substrates of the renal human organic anion transporter 4 (OAT4)
por: Louisse, Jochem, et al.
Publicado: (2022)

Prostate-Specific Antigen and Perfluoroalkyl Acids in the C8 Health Study Population
por: Ducatman, Alan, et al.
Publicado: (2015)

Stabilizing Halogen-Bonded Complex between Metallic Anion and Iodide
por: Ying, Fei, et al.
Publicado: (2022)

Removal of perfluoroalkyl acids and common drinking water contaminants by weak-base anion exchange resins: Impacts of solution pH and resin properties
por: Kassar, Christian, et al.
Publicado: (2022)

Light-driven, heterogeneous organocatalysts for C–C bond formation toward valuable perfluoroalkylated intermediates
por: Filippini, Giacomo, et al.
Publicado: (2020)

PERFLUOROALKYL ACIDS: What Is the Evidence Telling Us?
por: Betts, Kellyn S.
Publicado: (2007)

Aromatic and heterocyclic perfluoroalkyl sulfides. Methods of preparation
por: Boiko, Vladimir N
Publicado: (2010)

Mass Balance of Perfluoroalkyl Acids in the Baltic Sea
por: Filipovic, Marko, et al.
Publicado: (2013)

No association between perfluoroalkyl chemicals and hypertension in children
por: Geiger, Sarah Dee, et al.
Publicado: (2014)

Photo-organocatalytic Enantioselective Perfluoroalkylation of β-Ketoesters
por: Woźniak, Łukasz, et al.
Publicado: (2015)

The Madrid Statement on Poly- and Perfluoroalkyl Substances (PFASs)
por: Blum, Arlene, et al.
Publicado: (2015)

Synthesis of Antiviral Perfluoroalkyl Derivatives of Teicoplanin and Vancomycin
por: Bereczki, Ilona, et al.
Publicado: (2020)

Perfluoroalkyl and polyfluoroalkyl substances (PFAS) and their effects on the ovary
por: Ding, Ning, et al.
Publicado: (2020)

Exposure to Perfluoroalkyl Substances and Glucose Homeostasis in Youth
por: Goodrich, Jesse A., et al.
Publicado: (2021)

Perfluoroalkyl Substances in the Western Tropical Atlantic Ocean
por: Miranda, Daniele de A., et al.
Publicado: (2021)

Perfluoroalkyl Substances (PFASs) in the Canadian Freshwater Environment
por: Lalonde, Benoit, et al.
Publicado: (2022)

Photo enhanced degradation of polyfluoroalkyl and perfluoroalkyl substances
por: Olatunde, Olalekan C., et al.
Publicado: (2020)

The influences of perfluoroalkyl substances on the rheumatoid arthritis clinic
por: Zhao, Yun, et al.
Publicado: (2022)

Perfluoroalkyl substances in Baltic fish – the risk to consumers
por: Mikolajczyk, Szczepan, et al.
Publicado: (2023)

Ni(0)-promoted activation of C(sp(2))–H and C(sp(2))–O bonds
por: Min, Sehye, et al.
Publicado: (2021)

Ligand-Promoted Alkylation of C(sp(3))–H and C(sp(2))–H Bonds
por: Zhu, Ru-Yi, et al.
Publicado: (2014)

Perfluoroalkyl and Polyfluoroalkyl Substances in the Environment: Terminology, Classification, and Origins
por: Buck, Robert C, et al.
Publicado: (2011)

Level and temporal trend of perfluoroalkyl acids in Greenlandic Inuit
por: Long, Manhai, et al.
Publicado: (2012)

Do Perfluoroalkyl Compounds Impair Human Semen Quality?
por: Joensen, Ulla Nordström, et al.
Publicado: (2009)

Cannot write session to /tmp/vufind_sessions/sess_uhvmpsoba7vph7dvr4krgm30fv