Cargando…
N-Alkylation and N-Methylation of Amines with Alcohols Catalyzed by Nitrile-Substituted NHC–Ir(III) and NHC–Ru(II) Complexes
[Image: see text] A series of nitrile-modified N-heterocyclic carbene (NHC) complexes of Ir(III) (2a–e) and Ru(II) (3a–d) have been prepared by transmetallation of [IrCp*Cl(2)](2) and [RuCl(2)(p-cymene)](2) forming an in situ NHC–Ag complex. The structures of all complexes were characterized by (1)H...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9933218/ https://www.ncbi.nlm.nih.gov/pubmed/36816636 http://dx.doi.org/10.1021/acsomega.2c06341 |