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Borane-Protecting Strategy for Hydrosilylation of Phosphorus-Containing Olefins

[Image: see text] Ir-catalyzed hydrosilylation of the alkenyl phosphine borane complex 1 was achieved to give the corresponding products 2. Because the phosphino group coordinates with metals and is unstable under aerobic conditions, the formation of the corresponding borane adduct was effective not...

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Detalles Bibliográficos
Autores principales: Naganawa, Yuki, Fujita, Akira, Sakamoto, Kei, Tanaka, Shinji, Sato, Kazuhiko, Nakajima, Yumiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9933236/
https://www.ncbi.nlm.nih.gov/pubmed/36816693
http://dx.doi.org/10.1021/acsomega.2c07161