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Synthesis of a rhodium(iii) dinitrogen complex using a calix[4]arene-based diphosphine ligand
The synthesis and characterisation of the rhodium(iii) dinitrogen complex [Rh(2,2′-biphenyl)(CxP(2))(N(2))](+) are described, where CxP(2) is a trans-spanning calix[4]arene-based diphosphine and the dinitrogen ligand is projected into the cavity of the macrocycle.
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9933454/ https://www.ncbi.nlm.nih.gov/pubmed/36727440 http://dx.doi.org/10.1039/d2cc06837k |