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Pre-Equilibrium Reaction Mechanism as a Strategy to Enhance Rate and Lower Overpotential in Electrocatalysis

[Image: see text] Pre-equilibrium reaction kinetics enable the overall rate of a catalytic reaction to be orders of magnitude faster than the rate-determining step. Herein, we demonstrate how pre-equilibrium kinetics can be applied to breaking the linear free-energy relationship (LFER) for electroca...

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Detalles Bibliográficos
Autores principales: Pattanayak, Santanu, Berben, Louise A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9936576/
https://www.ncbi.nlm.nih.gov/pubmed/36734988
http://dx.doi.org/10.1021/jacs.2c10942