Cargando…
Metallomimetic Chemistry of a Cationic, Geometrically Constrained Phosphine in the Catalytic Hydrodefluorination and Amination of Ar–F Bonds
[Image: see text] The synthesis, isolation, and reactivity of a cationic, geometrically constrained σ(3)-P compound in the hexaphenyl-carbodiphosphoranyl-based pincer-type ligand (1(+)) are reported. 1(+) reacts with electron-poor fluoroarenes via an oxidative addition-type reaction of the C–F bond...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9936586/ https://www.ncbi.nlm.nih.gov/pubmed/36738474 http://dx.doi.org/10.1021/jacs.2c13318 |